111878-16-1

Basic information

• Product Name: 4-Chloro-benzoic acid (3R,3aR,6S,6aR)-6-hydroxy-hexahydro-furo[3,2-b]furan-3-yl ester
• Synonyms: 4-Chloro-benzoic acid (3R,3aR,6S,6aR)-6-hydroxy-hexahydro-furo[3,2-b]furan-3-yl ester
• CAS NO: 111878-16-1
• Molecular Weight: 284.696
• Mol File: 111878-16-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 4-Chloro-benzoic acid (3R,3aR,6S,6aR)-6-hydroxy-hexahydro-furo[3,2-b]furan-3-yl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 4-Chloro-benzoic acid (3R,3aR,6S,6aR)-6-hydroxy-hexahydro-furo[3,2-b]furan-3-yl ester(111878-16-1)
• EPA Substance Registry System: 4-Chloro-benzoic acid (3R,3aR,6S,6aR)-6-hydroxy-hexahydro-furo[3,2-b]furan-3-yl ester(111878-16-1)

Safety Data

• Hazardous Substances Data: 111878-16-1(Hazardous Substances Data)

Upstream product

• 790-41-0 4-chlorobenzoic anhydride 
• 652-67-5 Isosorbide 

Relevant articles and documents

Regioselective Acylation of 1,4:3,6-Dianhydro-D-glucitol

Acylation of 1,4:3,6-dianhydro-D-glucitol with anhydrides in the presence of heavy metal salts affords 5-endo-acylates with high regioselectivity, without detectable amounts of the isomeric 2-acylates.Acyl group migration occurs with preference for the 2-exo-position, on heating an acylation mixture, which contains varying amounts of 1,4:3,6-dianhydro-D-glucitol, 2- and 5-monoacylate and 2,5-diacylate, in the presence of reesterification catalysts and whilst distilling off the lower boiling 2-acylate.