111999-51-0

Basic information

• Product Name: Benzeneacetic acid, a-oxo-, 1-(chloromethyl)-2,2-dimethylhydrazide
• CAS NO: 111999-51-0
• Molecular Formula: C11H13ClN2O2
• Molecular Weight: 240.689
• Mol File: 111999-51-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Benzeneacetic acid, a-oxo-, 1-(chloromethyl)-2,2-dimethylhydrazide(CAS DataBase Reference)
• NIST Chemistry Reference: Benzeneacetic acid, a-oxo-, 1-(chloromethyl)-2,2-dimethylhydrazide(111999-51-0)
• EPA Substance Registry System: Benzeneacetic acid, a-oxo-, 1-(chloromethyl)-2,2-dimethylhydrazide(111999-51-0)

Safety Data

• Hazardous Substances Data: 111999-51-0(Hazardous Substances Data)

Upstream product

• 25726-04-9 phenylglyoxylyl chloride 
• 2035-89-4 N-methyl-N-(methyleneamino)methanamine 

Relevant articles and documents

Electrophilic Substitution Reaction at Azomethine Carbon Atom. Acylation of Aliphatic Aldehyde Hydrazones

Formaldehyde dialkylhydrazones were found to undergo an electrophilic substitution reaction very easily at the azomethine carbon atom when treated with trifluoroacetic anhydride.Bistrifluoroacetylation is also possible.As an interesting extension of this reaction, trifluoroacetylation of dialkylhydrazones of aliphatic aldehydes and α,β-unsaturated aldehydes, was achieved.Similar reactions of these hydrazones with some other acylating reagents were also studied.