112019-12-2

Basic information

• Product Name: Λ-Ru(OOC-t-Bu)2((S)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl)
• Synonyms: Λ-Ru(OOC-t-Bu)2((S)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl)
• CAS NO: 112019-12-2
• Molecular Weight: 926.006
• Mol File: 112019-12-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Λ-Ru(OOC-t-Bu)2((S)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl)(CAS DataBase Reference)
• NIST Chemistry Reference: Λ-Ru(OOC-t-Bu)2((S)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl)(112019-12-2)
• EPA Substance Registry System: Λ-Ru(OOC-t-Bu)2((S)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl)(112019-12-2)

Safety Data

• Hazardous Substances Data: 112019-12-2(Hazardous Substances Data)

Upstream product

• 50982-12-2 dichloro(1,5-cyclooctadiene)ruthenium(II) 
• 1184-88-9 sodium pivalate 
• 76189-55-4 (R)-(+)-2,2’-bis(diphenylphosphino)-1,1’-binaphthalene 

Downstream Products

• 440634-49-1 RuH(t-C₄H₉COO)[(S)-binap]P(C₆H₅) 

Relevant articles and documents

BINAP-ruthenium(II) dicarboxylate complexes: New, highly efficient catalysts for asymmetric hydrogenations

The BINAP-ruthenium(II) complexes Ru(OCOR)2[(R)- or (S)2,2′-bis(diarylphosphino)-1,1′-binaphthyl] [aryl = phenyl, p-tolyl; R = CH3, C(CH3)3] have been prepared. The crystal structure of Ru[OCOC(CH3)3] 2[(S)-2,2′-bis(diphenylphosphino)-1,1′-binaphthyl], determined by X-ray crystallography [diffraction data collected at -60°C, formula C54H50O4P2Ru, monoclinic, space group P21, Z = 2, a = 13.272 (2) A?, b = 16.224 (3) A?, c = 12.701 (2) A?, β = 124.34 (1)°, R = 0.037, Rw = 0.043], indicates that the monomeric ruthenium(II) complex has a distorted octahedron coordination geometry involving two phosphorus atoms of BINAP and four oxygen atoms of pivalate ligands. The complex has a Λ structure, while the BINAP-containing seven-membered chelate ring is fixed in a δ conformation. The molecular structure has been compared with that of Rh[(R)-BINAP](norbornadiene)ClO4. These BINAP-ruthenium complexes serve as highly efficient catalysts for asymmetric hydrogenations of various enamides, α-(acylamino)acrylic acids, α,β- and β,γ-unsaturated carboxylic acids, allylic and homoallylic alcohols, α-amino ketones, etc.