112033-25-7

Basic information

• Product Name: 1-(p-tolylsulphonylmethyl)-4-(1-cyano-1-methylethyl)-1-cyclohexene
• Synonyms: 1-(p-tolylsulphonylmethyl)-4-(1-cyano-1-methylethyl)-1-cyclohexene
• CAS NO: 112033-25-7
• Molecular Weight: 317.452
• Mol File: 112033-25-7.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 1-(p-tolylsulphonylmethyl)-4-(1-cyano-1-methylethyl)-1-cyclohexene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(p-tolylsulphonylmethyl)-4-(1-cyano-1-methylethyl)-1-cyclohexene(112033-25-7)
• EPA Substance Registry System: 1-(p-tolylsulphonylmethyl)-4-(1-cyano-1-methylethyl)-1-cyclohexene(112033-25-7)

Safety Data

• Hazardous Substances Data: 112033-25-7(Hazardous Substances Data)

Upstream product

• 19158-51-1 P-toluenesulfonyl cyanide 
• 127-91-3 (1R,5R)-(+)-β-pinene 
• 177698-19-0 Beta-pinene 

Relevant articles and documents

Catalytic, metal-free sulfonylcyanation of alkenes: Via visible light organophotoredox catalysis

The group transfer radical addition of olefins with tosyl cyanide has been accomplished via visible light-induced organophotoredox catalysis. A diverse array of olefins is amenable to this protocol, furnishing β-sulfonyl nitriles with excellent efficiency under metal-free and redox-neutral conditions. A closed catalytic cycle is operative in this transformation, providing complementary reactivity to the classic radical chain process.

FREE RADICAL TYPE ADDITION OF TOLUENESULFONYL CYANIDE TO UNSATURATED HYDROCARBONS

By catalysis of AIBN, tosyl cyanide adds in a regio- and stereoselective manner to unsaturated hydrocarbons, including alkenes, dienes and 1-hexyne.Accompanied intramolecular cyclization and ring cleavage were effected in reactions with norbornadiene, 1,5