112065-78-8

Basic information

• Product Name: Δ-Ru(OOCCH3)2((S)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl)
• Synonyms: Δ-Ru(OOCCH3)2((S)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl)
• CAS NO: 112065-78-8
• Molecular Weight: 897.952
• Mol File: 112065-78-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Δ-Ru(OOCCH3)2((S)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl)(CAS DataBase Reference)
• NIST Chemistry Reference: Δ-Ru(OOCCH3)2((S)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl)(112065-78-8)
• EPA Substance Registry System: Δ-Ru(OOCCH3)2((S)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl)(112065-78-8)

Safety Data

• Hazardous Substances Data: 112065-78-8(Hazardous Substances Data)

Upstream product

• 50982-12-2 dichloro(1,5-cyclooctadiene)ruthenium(II) 
• 153305-67-0 (R)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl 
• 127-09-3 sodium acetate 
• 153305-67-0 (+)-(R)-2,2'bis(di-para-tolylphosphanyl)-1,1'binaphthyl 
• 1034001-51-8 [RuCl(p-cymene)((R)-Tol-BINAP)]Cl 
• 52462-29-0 [ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂ 
• 99646-28-3 (R)-tol-BINAP 

Relevant articles and documents

METHOD FOR PRODUCING A RUTHENIUM COMPLEX

Provided is a method for producing a ruthenium complex comprises the step of reacting a ruthenium compound represented by general formula (1): [in-line-formulae][RuX(L)(PP)]X ??(1),[/in-line-formulae] wherein Ru represents a ruthenium atom; X represents a halogen atom; L represents an arene; and PP represents an optically active bisphosphine, with a carboxylate salt represented by general formula (2): [in-line-formulae]R1CO2M ??(2),[/in-line-formulae] wherein M represents a monovalent cation; and R1 represents a group selected from the group consisting of alkyl groups, haloalkyl groups, phenyl groups optionally having a substituent(s), 1-aminoalkyl groups and 1-amino-1-phenylalkyl groups, to produce a ruthenium complex represented by general formula (3): [in-line-formulae]Ru(OCOR1)2(PP) ??(3),[/in-line-formulae] wherein R1 represents the group selected from the group consisting of alkyl groups, haloalkyl groups, phenyl groups optionally having a substituent(s), 1-aminoalkyl groups and 1-amino-1-phenylalkyl groups; and PP represents the optically active bisphosphine.