1122103-26-7Relevant articles and documents
Environmentally friendly organic synthesis using bismuth compounds. bismuth trifluoromethanesulfonate-catalyzed allylation of dioxolanes
Spafford, Matthew J.,Christensen, James E.,Huddle, Matthew G.,Lacey, Joshua R.,Mohan, Ram S.
, p. 419 - 421 (2008/09/21)
A bismuth trifluoromethanesulfonate (triflate)-catalyzed (2.0 mol-%) multicomponent reaction involving the allylation of dioxolanes followed by in situ derivatization with anhydrides to generate highly functionalized esters has been developed under solvent-free conditions. Most reagents used to date for allylation of dioxolanes are highly corrosive and are often required in stoichiometric amounts. In contrast, the use of a relatively non-toxic and non-corrosive bismuth(iii)-based catalyst makes this methodology especially attractive for scale-up. CSIRO 2008.
