112483-13-3Relevant articles and documents
A Regioselective One Pot Synthesis and Synthetic Applications of Cyanodeoxy Sugars by Cyanotrimethylsilane
Kazmi, Syed Najam-ul-Hussain,Ahmed, Zaheer,Malik, Abdul,Afza, Nighat,Voelter, Wolfgang
, p. 294 - 302 (2007/10/02)
The regioselective epoxide opening of different 2,3-anhydropyranoses by cyanotrimethylsilane is investigated.The isolated cyanodeoxy pyranoses allow easy access to the corresponding branched-chains aminomethyl sugars by lithium aluminium hydride reduction
REGIOSELECTIVE ONE POT SYNTHESES OF CYANODEOXY SUGARS
Kazmi, Syed Najam-ul-Hussain,Ahmed, Zaheer,Khan, Abdul Qasim,Malik, Abdul
, p. 151 - 156 (2007/10/02)
A rapid high yielding regioselective approach to cyanodeoxy sugars (5-8) has been developed by way of trans diaxial cleavage of the oxirane ring in 2,3-anhydro sugars (1-4) with cyanotrimethylsilane using aluminium chloride as catalyst.