112518-87-3

Basic information

• Product Name: 1(2H)-Quinolinecarboxylic acid, 2-(2-propynyl)-, methyl ester
• CAS NO: 112518-87-3
• Molecular Formula: C14H13NO2
• Molecular Weight: 227.263
• Mol File: 112518-87-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1(2H)-Quinolinecarboxylic acid, 2-(2-propynyl)-, methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 1(2H)-Quinolinecarboxylic acid, 2-(2-propynyl)-, methyl ester(112518-87-3)
• EPA Substance Registry System: 1(2H)-Quinolinecarboxylic acid, 2-(2-propynyl)-, methyl ester(112518-87-3)

Safety Data

• Hazardous Substances Data: 112518-87-3(Hazardous Substances Data)

Upstream product

• 91-22-5 quinoline 
• 53915-69-8 allenyltributylstannane 
• 79-22-1 methyl chloroformate 

Relevant articles and documents

Reactions of Allenylic Tin Reagents to N-Alkoxycarbonyl-isoquinolinium and -quinolinium Salts. Effective Introduction of 2-Alkynylic Groups to Isoquinoline and Quinoline Systems

Reaction of allenylic tin reagents with isoquinoline in the presence of chloroformate esters as acylating agents give 2-alkoxycarbonyl-1-(2-alkynyl)-1,2-dihydroisoquinolines in good to excellent yields.Similarly, the reactions with quinoline give 1- alkoxycarbonyl-2-(2-alkynyl)-1,2-dihydroquinolines exclusively.