112563-60-7

Basic information

• Product Name: (1RS,3SR,6RS)-8-Oxo-7-azabicyclo<4.2.0>oct-4-en-3-yl benzoate
• CAS NO: 112563-60-7
• Molecular Weight: 243.262
• Mol File: 112563-60-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (1RS,3SR,6RS)-8-Oxo-7-azabicyclo<4.2.0>oct-4-en-3-yl benzoate(CAS DataBase Reference)
• NIST Chemistry Reference: (1RS,3SR,6RS)-8-Oxo-7-azabicyclo<4.2.0>oct-4-en-3-yl benzoate(112563-60-7)
• EPA Substance Registry System: (1RS,3SR,6RS)-8-Oxo-7-azabicyclo<4.2.0>oct-4-en-3-yl benzoate(112563-60-7)

Safety Data

• Hazardous Substances Data: 112563-60-7(Hazardous Substances Data)

Upstream product

• 614-45-9 tert-Butyl peroxybenzoate 
• 98810-97-0 (1RS,6SR)-7-Dimethyl-tert-butylsilyl-7-azabicyclo<4.2.0>oct-3-en-8-one 
• 20205-48-5 8-oxo-7-azabicyclo<4.2.0>oct-2-ene 
• 112563-55-0 Benzoic acid (1S,5R,6S)-7-(tert-butyl-dimethyl-silanyl)-8-oxo-7-aza-bicyclo[4.2.0]oct-3-en-5-yl ester 
• 112563-56-1 (1RS,6RS)-7-Diphenyl-tert-butylsilyl-7-azabicyclo<4.2.0>oct-3-en-8-one 
• 112563-54-9 Benzoic acid (1S,6R)-7-(tert-butyl-dimethyl-silanyl)-8-oxo-7-aza-bicyclo[4.2.0]oct-4-en-3-yl ester 

Relevant articles and documents

Olivanic Acid Analogues. Part 9. Allylic Oxidative Functionalisation of Substituted Azetidinones: Synthesis of Some 4-Acyloxy-7-oxo-1-azabicyclohept-2-ene-2-carboxylates

Sharpless oxidation (ButO2H), SeO2) of the protected allyl azetidinone 7 gave the allylic alcohol 8 which was transformed to the 5,6-trans-4α-acetoxyolivanic acid derivative 16.Kharasch-Sosnovsky benzoyloxylation (PhCO3But, CuCl, PhH, heat) of the silylated 7-azabicyclooct-3-enes 17b,c provided inter alia allylic benzoates 18b,c and 21b,c.These were synthetic precursors of the 5,6-cis-olivanic acid analogues 23 and 26, which contain 8- and 4α-benzoyloxy groups, respectively.