1128-78-5Relevant articles and documents
Oxidation of methyl groups by grass grubs and vertebrate liver enzymes.
Hook,Smith
, p. 504 - 510 (1967)
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Contra-thermodynamic trans-esteripication of carbamates by counter-attack strategy: A viable non-phosgene, non-mic route to carbamate pesticides
Kulkarni,Naik,Tandel,Rajappa
, p. 1249 - 1256 (2007/10/02)
Treatment of methyl N-methylcarbaaate (1, R= Me) with phosphorus oxychloride and 1-naphthol results in the formation of the transesterified product, 1-naphthyl N-methylcarbamate (2, Ar=1-naphthy 1) in good yield. Similarly, ethyl N-methylthiocarbamate (5) is converted to 1-naphthyl N-methylcarbamate (2, Ar= 1-naphthyl) on treatment with phosphorus oxychloride and 1-naphthol. The mechanism of these interesting and industrially important transformations is discussed.