112835-82-2Relevant articles and documents
Obtention d'α-fluorocetones par oxydation anodique de derives d'enol.
Laurent, E.,Marquet, B,Tardivel, R.,Thiebault, H.
, p. 955 - 964 (2007/10/02)
To obtain fluoroketones without the use of electrophilic fluorinating reagents, we have carried out the anodic oxidation of enol esters and enol ethers in acetonitrile/Et3N, 3HF solution.With enol esters the main product is a fluoroketone or an acetoxyketone respectively, depending on the structure of the starting compound.The enol ether cation-radicals seemed to be less reactive towards H2F3- ions than the corresponding enol ester ones.