113034-04-1Relevant articles and documents
METHYLPHOSPHONIC DICHLORIDE AS REAGENT FOR THE DETERMINATION OF THE ENANTIOMERIC EXCESS OF CHIRAL THIOLS. SCOPE AND LIMITATIONS
Strijtveen, Bert,Feringa, Ben L.,Kellogg, Richard M.
, p. 123 - 130 (1987)
Methylphosphonic dichloride, CH3P(=O)Cl2, reacts cleanly and quantitatively with thiols to form dialkylthiophosphonates, CH3P(=O)(SR)2.From the ratio of the integrations of the 31P absorptions in the NMR spectra, the enantiomeric excesses of the thiols ca