1132641-33-8

Basic information

• Product Name: methyl 2-(((tert-butoxycarbonyl)oxy)(3,4-dichlorophenyl)methyl)acrylate
• Synonyms: methyl 2-(((tert-butoxycarbonyl)oxy)(3,4-dichlorophenyl)methyl)acrylate
• CAS NO: 1132641-33-8
• Molecular Weight: 361.222
• Mol File: 1132641-33-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: methyl 2-(((tert-butoxycarbonyl)oxy)(3,4-dichlorophenyl)methyl)acrylate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 2-(((tert-butoxycarbonyl)oxy)(3,4-dichlorophenyl)methyl)acrylate(1132641-33-8)
• EPA Substance Registry System: methyl 2-(((tert-butoxycarbonyl)oxy)(3,4-dichlorophenyl)methyl)acrylate(1132641-33-8)

Safety Data

• Hazardous Substances Data: 1132641-33-8(Hazardous Substances Data)

Upstream product

• 24424-99-5 di-tert-butyl dicarbonate 

Relevant articles and documents

Enantioselective dearomative [3+2] cycloaddition of 2-nitrobenzofurans with aldehyde-derived Morita-Baylis-Hillman carbonates

The phosphine-catalyzed asymmetric dearomative [3+2] cycloaddition of 2-nitrobenzofurans with aldehyde-derived Morita-Baylis-Hillman (MBH) carbonates or allenoate was developed. The reaction with MBH carbonates resulted in a series of cyclopentabenzofurans containing three contiguous stereocenters with good to high yields, diastereoselectivities and enantioselectivities. The use of allenoate also gave the target product with moderate enantioselectivity.