113365-35-8

Basic information

• Product Name: Benzonitrile, 4-(1-hydroxy-2,2-dimethyl-3-butenyl)-
• CAS NO: 113365-35-8
• Molecular Formula: C13H15NO
• Molecular Weight: 201.268
• Mol File: 113365-35-8.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: Benzonitrile, 4-(1-hydroxy-2,2-dimethyl-3-butenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzonitrile, 4-(1-hydroxy-2,2-dimethyl-3-butenyl)-(113365-35-8)
• EPA Substance Registry System: Benzonitrile, 4-(1-hydroxy-2,2-dimethyl-3-butenyl)-(113365-35-8)

Safety Data

• Hazardous Substances Data: 113365-35-8(Hazardous Substances Data)

Upstream product

• 598-25-4 Dimethylallene 
• 105-07-7 4-cyanobenzaldehyde 
• 78-79-5 isoprene 
• 114571-77-6 triethylammonium bis(catecholato)(3-methyl-2-butenyl)siliconate 
• 17314-40-8 3-Methyl-2-butenyl-trimethylstannane 
• 114067-34-4 (3-methyl-2-butenyl)trifluorosilane 

Relevant articles and documents

Palladium-catalysed Carbonyl Allylation by Isoprene via Regioselective 1,4-Addition of Tin Hydride formed in situ

Isoprene reacts with aldehydes in the presence of a catalytic amount of Pd(OAc)2-4PPh3 or Pd(PPh3)4 and a stoichiometric amount of SnCl2 at 40-50 deg C in AcOH-H2O to produce 1-substituted 2,2-dimethyl-3-buten-1-ols regioselectively.

Highly regioselective and stereoselective allylation of aldehydes via palladium-catalyzed in situ hydrostannylation of allenes

(Equation presented) Highly regio-and stereoselective allylalion of aldehydes by allenes proceeds smoothly in aqueous/organic media in the presence of PdCl2-(PPh3)2, HCl, and SnCl2. The reaction likely occurs via hydrostannylation of allenes and allylation of aldehydes by the in situ generated allyltrichlorotins to afford the final products.

Highly stereoselective allylation of aldehydes with pentacoordinate allylsilicates in hydroxylic media. Discrimination between linear and α-branched alkanals1

Allylation of aldehydes with allyltrifluorosilanes in the presence of a wide variety of hydroxy compounds and triethylamine gave the corresponding homoallyl alcohols in regio- and stereospecific manner. Pentacoordinate allylsilicates are suggested as inte