113419-02-6

Basic information

• Product Name: 1-Benzyl-2,4,6-trimethyl-4-<1'-benzyl-2',6'-dimethylen-4'-methyl-piperidin-4-yl>-1,4-dihydropyridin
• CAS NO: 113419-02-6
• Molecular Weight: 424.629
• Mol File: 113419-02-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-Benzyl-2,4,6-trimethyl-4-<1'-benzyl-2',6'-dimethylen-4'-methyl-piperidin-4-yl>-1,4-dihydropyridin(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Benzyl-2,4,6-trimethyl-4-<1'-benzyl-2',6'-dimethylen-4'-methyl-piperidin-4-yl>-1,4-dihydropyridin(113419-02-6)
• EPA Substance Registry System: 1-Benzyl-2,4,6-trimethyl-4-<1'-benzyl-2',6'-dimethylen-4'-methyl-piperidin-4-yl>-1,4-dihydropyridin(113419-02-6)

Safety Data

• Hazardous Substances Data: 113419-02-6(Hazardous Substances Data)

Upstream product

• 113402-71-4 1,1'-Dibenzyl-2,4,6,2',4',6'-hexamethyl-1,4,1',4'-tetrahydro-[4,4']bipyridyl 

Downstream Products

• 117600-80-3 N-{2-[1,1'-Dibenzyl-4,2',4',6'-tetramethyl-6-methylene-3,4,5,6,1',4'-hexahydro-1H-[4,4']bipyridinyl-(2E)-ylidene]-thioacetyl}-benzamide 
• 113402-64-5 1,2,4,6,7,9-Hexamethyl-3,10-dibenzyl-3,10-diaza-tricyclo-<5.3.1.1.^2,6>dodeca-4,8-dien 

Relevant articles and documents

Electrochemistry of Organic Cations. V. Synthesis of 3,10-Diaza-tricyclo2,6>dodeca-4,8-diene Derivatives by a Two-Step Electrochemical Reduction of Pyridinium Ions

A series of 1-substituted 2,4,6-trimethylpyridinium ions 1a-1k is cathodically dimerized in alkaline medium.The bis--derivatives 2 obtained or their isomers 4 are submitted to a further cathodic reduction in aqueous acetic acid at mercury or lead electrodes to form 3,10-diaza-tricyclo2,6>dodeca-4,8-dienes 6 by an intramolecular coupling reaction between the 2- and 2'-carbon atoms of the dihydropyridine rings.Depending on R1 the yields of 6 are 65-80percent (R1 = alkyl or substituted alkyl) or 3,5-5percent (R1 = aryl).