113436-59-2

Basic information

• Product Name: (E)-(1-deuterio-2-nitroethenyl)benzene
• Synonyms: (E)-(1-deuterio-2-nitroethenyl)benzene
• CAS NO: 113436-59-2
• Molecular Weight: 150.141
• Mol File: 113436-59-2.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: (E)-(1-deuterio-2-nitroethenyl)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-(1-deuterio-2-nitroethenyl)benzene(113436-59-2)
• EPA Substance Registry System: (E)-(1-deuterio-2-nitroethenyl)benzene(113436-59-2)

Safety Data

• Hazardous Substances Data: 113436-59-2(Hazardous Substances Data)

Upstream product

• 3592-47-0 Benzaldehyde-d 
• 75-52-5 nitromethane 
• 5153-67-3 nitrostyrene 

Downstream Products

• 13706-68-8 (+-)-phenylsuccinonitrile 
• 113436-76-3 C₂₆H₂₃⁽²⁾HN₂O₆ 
• 83612-44-6 C₁₈H₁₇⁽²⁾HN₂O₂ 

Relevant articles and documents

Straightforward synthesis of 1,2-dicyanoalkanes from nitroalkenes and silyl cyanide mediated by tetrabutylammonium fluoride

A straightforward synthesis of 1,2-dicyanoalkanes by reacting nitroalkenes with trimethylsilyl cyanide in the presence of tetrabutylammonium fluoride is described. The reaction proceeds through a tandem double Michael addition under mild conditions. Employing the hypervalent silicate generated from trimethylsilyl cyanide and tetrabutylammonium fluoride is essential for achieving this transformation. Mechanistic studies suggest that a small amount of water included in the reaction media plays a key role. This protocol is applicable to various types of substrates including electron-rich and electron-deficient aromatic nitroalkenes, and aliphatic nitroalkenes. Moreover, vinyl sulfones were found to be good alternatives, particularly for electron-deficient nitroalkenes. The broad substrate scope and functional group tolerance of the reaction makes this approach a practical method for the synthesis of valuable 1,2-dicyanoalkanes.

Synthesis and properties of azoles and their derivatives. Part LXII. Secondary deuterium kinetic isotope effects in [2+3] cycloaddition of (E)-2-phenylnitroethene to (Z)-C,N-diphenylnitrone

SKIE analysis of [2+3] cycloaddition of (E)-2-phenylnitroethene to (Z)-C,N-diphenyl-nitrone suggests that for both stereoisomeric reaction paths (Scheme 1 ), the 01-C5 bond of the adduct forms faster than the corresponding C3-C4 bond. Nevertheless, both s

Cycloadditions dipolaires 1,3 aux derives nitres α ethyleniques, acetyleniques potentiels. I. Reaction avec des ylures d'azomethine. Orientation et stereochimie de la cycloaddition

The stereochemistry of the nitroolefins 1 prepared by known methods was unambigously established.Their reactions with azomethine ylides (e.g. 8) was studied and the stereochemistry of the adducts as well.This preliminary work was necessary to substantiate a discussion of structural (pyrrolidines conformational analysis) and mechanistic problems (dipolarophile-azomethine ylide approach and HNO2 elimination from the nitro pyrrolidines).