113490-26-9

Basic information

• Product Name: Peroxide, bis([1,1'-biphenyl]-4-ylcarbonyl)
• CAS NO: 113490-26-9
• Molecular Formula: C26H18O4
• Molecular Weight: 394.427
• Mol File: 113490-26-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Peroxide, bis([1,1'-biphenyl]-4-ylcarbonyl)(CAS DataBase Reference)
• NIST Chemistry Reference: Peroxide, bis([1,1'-biphenyl]-4-ylcarbonyl)(113490-26-9)
• EPA Substance Registry System: Peroxide, bis([1,1'-biphenyl]-4-ylcarbonyl)(113490-26-9)

Safety Data

• Hazardous Substances Data: 113490-26-9(Hazardous Substances Data)

Upstream product

• 14002-51-8 4-biphenyl-carboxylic acid chloride 

Downstream Products

• 92-52-4 biphenyl 
• 15719-64-9 methylammonium carbonate 
• 92-92-2 biphenyl-4-carboxylic acid 
• 630-76-2 tetraphenylmethane 
• 92-94-4 [1,1';4',1'']terphenyl 
• 28358-56-7 4-Biphenyl-biphenyl-4-carboxylat 
• 78322-97-1 phenyl [1,1′-biphenyl]-4-carboxylate 
• 4499-83-6 para-hexaphenyl 

Relevant articles and documents

Uncatalyzed, on water oxygenative cleavage of inert C-N bond with concomitant 8,7-amino shift in 8-aminoquinoline derivatives

Oxygenative cleavage of an inert CAr-NH2 bond with concomitant 1,2 amine migration in 8-aminoquinoline derivatives is reported in water at room temperature. The reaction is highly atom- and step-economical as both C- and N-containing fragments of the C-N bond cleavage are incorporated into the target molecule and is effected without the need for N-oxide. The reaction is scalable to gram level, and the products are useful as electrophilic partners for coupling reactions, ligands in catalysis and bioactive compounds.