113556-00-6

Basic information

• Product Name: p-(dimethylamino)phenyl dodecyl sulfide
• Synonyms: p-(dimethylamino)phenyl dodecyl sulfide
• CAS NO: 113556-00-6
• Molecular Weight: 321.571
• Mol File: 113556-00-6.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: p-(dimethylamino)phenyl dodecyl sulfide(CAS DataBase Reference)
• NIST Chemistry Reference: p-(dimethylamino)phenyl dodecyl sulfide(113556-00-6)
• EPA Substance Registry System: p-(dimethylamino)phenyl dodecyl sulfide(113556-00-6)

Safety Data

• Hazardous Substances Data: 113556-00-6(Hazardous Substances Data)

Upstream product

• 5397-29-5 4-(N,N-dimethylamino)phenyl disulfide 
• 143-15-7 1-dodecylbromide 
• 2757-37-1 didodecyl disulfide 
• 7353-91-5 4-dimethylaminophenylmagnesium bromide 
• 112-55-0 1-dodecylthiol 
• 1197-19-9 4-cyano-N,N-dimethylaniline 

Downstream Products

• 13330-29-5 4-n-butyl-N,N-dimethylaniline 
• 4139-78-0 4-isopropyl-N,N-dimethylaniline 
• 71089-15-1 1-(4-N,N-dimethylaminophenyl)propane 

Relevant articles and documents

Nickel-Catalyzed Thiolation of Aryl Nitriles

A nickel-catalyzed thiolation of aryl nitriles has been developed to access functionalized aryl thioethers. The ligand dcype (1,2-bis(dicyclohexylphosphino)ethane) as well as the base KOtBu (potassium tert-butoxide) are essential to achieve this transformation. This scalable and practical process involves both a C?C bond activation and a C?S bond formation. Furthermore, this reaction shows a high functional-group tolerance and enables the late-stage functionalization of important molecules.

Nickel-catalyzed cross-coupling reactions of alkyl aryl sulfides and alkenyl alkyl sulfides with alkyl grignard reagents using (Z)-3,3-dimethyl-1,2- bis(diphenylphosphino)but-1-ene as ligand

A combination of nickel(II) acetylacetonate and (Z)-3,3-dimethyl-1,2- bis(diphenylphosphino)but-1-ene catalyzes cross-coupling reactions of alkyl aryl sulfides and alkenyl alkyl sulfides with alkyl Grignard reagents. Not only primary but also secondary alkyl Grignard reagents can be employed. Georg Thieme Verlag Stuttgart.