113557-35-0

Basic information

• Product Name: 2-bromo-N-(2,3-dimethoxybenzyl)-4,5-methylenedioxyphenethylamine
• Synonyms: 2-bromo-N-(2,3-dimethoxybenzyl)-4,5-methylenedioxyphenethylamine
• CAS NO: 113557-35-0
• Molecular Weight: 394.265
• Mol File: 113557-35-0.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 2-bromo-N-(2,3-dimethoxybenzyl)-4,5-methylenedioxyphenethylamine(CAS DataBase Reference)
• NIST Chemistry Reference: 2-bromo-N-(2,3-dimethoxybenzyl)-4,5-methylenedioxyphenethylamine(113557-35-0)
• EPA Substance Registry System: 2-bromo-N-(2,3-dimethoxybenzyl)-4,5-methylenedioxyphenethylamine(113557-35-0)

Safety Data

• Hazardous Substances Data: 113557-35-0(Hazardous Substances Data)

Upstream product

• 86-51-1 2,3-dimethyoxybenzaldehyde 
• 63375-82-6 2-(6-bromo-benzo[1,3]dioxol-5-yl)-ethylamine 

Downstream Products

• 483-15-8 7,8-dihydroberberine 

Relevant articles and documents

Convenient synthesis of 2,3,9,10-tetraoxygenated protoberberine alkaloids and their 13-methyl alkaloids

New and convenient synthesis of 2,3,9,10-tetraoxygenated protoberberine alkaloids and their 13-methyl alkaloids through the same intermediates was developed. Acylation of the brominated benzylphenethylamine (13) with α- chloro-α-(methylthio)acetyl chloride, followed by cyclization with stannic chloride, furnished the key intermediates 4-methylthio-3- phenethylisoquinolin-3-ones (14), which were methylated to provide their methyl derivatives (17). Both isoquinolin-3-ones (14, 17) were easily transformed into protoberberine alkaloids (16) and their 13-methyl alkaloids (21) in good yield.