113599-63-6

Basic information

• Product Name: allyl 2-<(3S,4S)-4-<<(tert-butyldimethylsilyl)oxy>methyl>-2-oxo-3-tritylamino-1-azetidinyl>-3-oxo-5-(phenylseleno)pentanoate
• Synonyms: allyl 2-<(3S,4S)-4-<<(tert-butyldimethylsilyl)oxy>methyl>-2-oxo-3-tritylamino-1-azetidinyl>-3-oxo-5-(phenylseleno)pentanoate
• CAS NO: 113599-63-6
• Molecular Weight: 781.926
• Mol File: 113599-63-6.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: allyl 2-<(3S,4S)-4-<<(tert-butyldimethylsilyl)oxy>methyl>-2-oxo-3-tritylamino-1-azetidinyl>-3-oxo-5-(phenylseleno)pentanoate(CAS DataBase Reference)
• NIST Chemistry Reference: allyl 2-<(3S,4S)-4-<<(tert-butyldimethylsilyl)oxy>methyl>-2-oxo-3-tritylamino-1-azetidinyl>-3-oxo-5-(phenylseleno)pentanoate(113599-63-6)
• EPA Substance Registry System: allyl 2-<(3S,4S)-4-<<(tert-butyldimethylsilyl)oxy>methyl>-2-oxo-3-tritylamino-1-azetidinyl>-3-oxo-5-(phenylseleno)pentanoate(113599-63-6)

Safety Data

• Hazardous Substances Data: 113599-63-6(Hazardous Substances Data)

Upstream product

• 1393717-48-0 C₁₆H₃₆N⁽¹⁺⁾*C₁₈H₂₇N₂O₇SSi^(1-) 
• 113599-61-4 (3S,4S)-4-<<(tert-butyldimethylsilyl)oxy>methyl>-3-(tritylamino)-2-azetidinone 
• 113599-60-3 (3S,4S)-3-(benzyloxycarboxamido)-4-<<(tert-butyldimethylsilyl)oxy>methyl>-2-azetidinone 
• 113599-59-0 (3S,4S)-3-Amino-4-(tert-butyl-dimethyl-silanyloxymethyl)-azetidin-2-one 
• 18162-48-6 tert-butyldimethylsilyl chloride 
• 76-83-5 trityl chloride 
• 16599-78-3 3-(phenylselanyl)propanoic acid 
• 40630-84-0 allyl bromoacetate 
• 113600-04-7 3-(phenylseleno)propionyl chloride 

Downstream Products

• 113600-00-3 (6S,7S)-7-<<(R)-2-(4-hydroxyphenyl)glycyl>amino>-8-oxo-1-aza-4-oxabicyclo<4.2.0>oct-2-ene-2-carboxylic acid 
• 113600-01-4 (6S,7S)-7-<<(R)-2-(4-hydroxyphenyl)glycyl>amino>-3-methyl-8-oxo-1-aza-4-oxabicyclo<4.2.0>oct-2-ene-2-carboxylic acid 
• 113599-99-8 (6S,7S)-7-<<(R)-2-(4-hydroxyphenyl)glycyl>amino>-8-oxo-3-(2-propenyl)-1-aza-4-oxabicyclo<4.2.0>oct-2-ene-2-carboxylic acid 
• 113600-02-5 (6S,7S)-7-<<(R)-2-(4-hydroxyphenyl)glycyl>amino>-3-propyl-8-oxo-1-aza-4-oxabicyclo<4.2.0>oct-2-ene-2-carboxylic acid 
• 113600-03-6 (6S,7S)-7-<<(R)-2-(4-hydroxyphenyl)glycyl>amino>-3-cyclopropyl-8-oxo-1-aza-4-oxabicyclo<4.2.0>oct-2-ene-2-carboxylic acid 
• 113599-80-7 allyl (6S,7S)-8-oxo-7-(tritylamino)-1-aza-4-oxabicyclo<4.2.0>oct-2-ene-2-carboxylate 
• 113599-73-8 allyl 2-<(3S,4S)-4-(hydroxymethyl)-2-oxo-3-tritylamino-1-azetidinyl>-3-oxopropanoate 
• 113599-86-3 allyl (6S,7S)-7-<<(R)-N-<(allyloxy)carbonyl>-2-(4-hydroxyphenyl)glycyl>amino>-8-oxo-1-aza-4-oxabicyclo<4.2.0>oct-2-ene-2-carboxylate 
• 113627-35-3 allyl (6S,7S)-3-propyl-8-oxo-7-(tritylamino)-1-aza-4-oxabicyclo<4.2.0>oct-2-ene-2-carboxylate 
• 113599-87-4 (6S,7S)-7-[(R)-2-Allyloxycarbonylamino-2-(4-hydroxy-phenyl)-acetylamino]-3-methyl-8-oxo-4-oxa-1-aza-bicyclo[4.2.0]oct-2-ene-2-carboxylic acid allyl ester 
• 113599-75-0 allyl 2-<(3S,4S)-4-(hydroxymethyl)-2-oxo-3-tritylamino-1-azetidinyl>-3-oxohexanoate 
• 113599-84-1 allyl (6S,7S)-7-<<(R)-N-<(allyloxy)carbonyl>-2-(4-hydroxyphenyl)glycyl>amino>-3-(chloromethyl)-8-oxo-1-aza-4-oxabicyclo<4.2.0>oct-2-ene-2-carboxylate 
• 113599-92-1 (6S,7S)-7-[(R)-2-Allyloxycarbonylamino-2-(4-hydroxy-phenyl)-acetylamino]-3-iodomethyl-8-oxo-4-oxa-1-aza-bicyclo[4.2.0]oct-2-ene-2-carboxylic acid allyl ester 
• 113599-88-5 (6S,7S)-7-[(R)-2-Allyloxycarbonylamino-2-(4-hydroxy-phenyl)-acetylamino]-8-oxo-3-propyl-4-oxa-1-aza-bicyclo[4.2.0]oct-2-ene-2-carboxylic acid allyl ester 

Relevant articles and documents

Design, synthesis and antibacterial activities of a series of new 2-oxaisocephems

A series of 2-oxaisocephems with a thio-substituted methyl group at the 3-position and a [2-(5-amino-1,2,4-thiadizol-3-yl)-2-(Z)-alkoxyimino]acetamido moiety at 7-position were synthesized and tested for their antibacterial activities. The analogs 17c and 17f have well-balanced potency and significantly enhanced activity as compared with the reference compound ceftazidime.

A General Enantioselective O-2-Isocephem Synthesis

A simple procedure for the conversion of the readily available chiral azetidinone (2) into the O-2-isocephem (5) is described.