113639-18-2Relevant articles and documents
ACETYLENIC FRAGMENTATION OF ACYL DERIVATIVES OF THE FISCHER BASE
Prizhiyalgovskaya, N. M.,Kon'kov, L. I.,Tarshits, D. L.,Salmina, S. V.,Segizova, N. T.,Suvorov, N. N.
, p. 751 - 754 (2007/10/02)
Indolenium salts, which readily undergo cleavage in aqueous alkali to give a monosubstituted acetylene and 1,3,3-trimethyl-2-oxindole, are formed when acyl derivatives of the Fischer base are heated with phosphorus oxychloride.Various aryl- and hetarylacetylenes can be conveniently obtained by this method.