113872-74-5

Basic information

• Product Name: PtCl₂(pyridine-2-CHN₆H₄OMe-p)
• Synonyms: PtCl₂(pyridine-2-CHN₆H₄OMe-p)
• CAS NO: 113872-74-5
• Molecular Weight: 478.237
• Mol File: 113872-74-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: PtCl₂(pyridine-2-CHN₆H₄OMe-p)(CAS DataBase Reference)
• NIST Chemistry Reference: PtCl₂(pyridine-2-CHN₆H₄OMe-p)(113872-74-5)
• EPA Substance Registry System: PtCl₂(pyridine-2-CHN₆H₄OMe-p)(113872-74-5)

Safety Data

• Hazardous Substances Data: 113872-74-5(Hazardous Substances Data)

Upstream product

• 10025-99-7 potassium tetrachloroplatinate(II) 
• 26930-67-6 N-(pyrid-2-ylmethylene)-p-methoxyphenylamine 
• 16405-35-9 Zeise's salt 
• 113872-72-3 PtCl₂(C₆H₄OMe-p)NCHCHN(C₆H₄OMe-p) 

Downstream Products

• 13965-31-6 dichloro(2,2'-bipyridine)platinum(II) 
• 113872-72-3 PtCl₂(C₆H₄OMe-p)NCHCHN(C₆H₄OMe-p) 
• 7440-06-4 platinum 

Relevant articles and documents

Solid- and solution phase synthesis of diiminedichloroplatinum(II) complexes

A solid-phase and solution phase synthesis approach for diiminedichloro complexes of platinum(II) was developed. In particular a dichloroplatinum(II) fragment was coordinated to the diimine ligands {4-[(pyridine-2-ylmethylene)- amino]-phenol, HO-N∩N′ (1); 4-[(pyridine-2-ylmethylene)-amino]- anisole, MeO-N∩N′ (2) and di-isopropylsilylpolystyrene immobilised 4-[(pyridine-2-ylmethylene)-amino]-phenolate PSO-N∩N′, (5)}. Identities of the compounds [PtIICl2(HO-N∩N′)] (3), [PtIICl2(MeO-N∩N′)] (4), [Pt IICl2(PSO-N∩N′)] (6) and 3 obtained by cleavage from 6 were established by multinuclear NMR spectroscopy, by microanalysis and single-crystal diffraction (3 and 4). Structures of compounds 3 and 4 were discussed with the aid of DFT calculations.