113977-51-8Relevant articles and documents
Binaphthol-catalyzed asymmetric conjugate arylboration of enones
Turner, Heather M.,Patel, Jignesh,Niljianskul, Nootaree,Chong, J. Michael
supporting information; experimental part, p. 5796 - 5799 (2012/01/06)
Conjugate addition of arylboronates to α,β-unsaturated ketones may be catalyzed by chiral binaphthols with enantioselectivities of up to 99:1. Best results were observed with 3,3′-dichloro-BINOL. This chemistry was applied to syntheses of intermediates fo