114067-38-8

Basic information

• Product Name: 1,5-Hexadien-3-ol, 4,4-dimethyl-1-phenyl-
• CAS NO: 114067-38-8
• Molecular Formula: C14H18O
• Molecular Weight: 202.296
• Mol File: 114067-38-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 1,5-Hexadien-3-ol, 4,4-dimethyl-1-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,5-Hexadien-3-ol, 4,4-dimethyl-1-phenyl-(114067-38-8)
• EPA Substance Registry System: 1,5-Hexadien-3-ol, 4,4-dimethyl-1-phenyl-(114067-38-8)

Safety Data

• Hazardous Substances Data: 114067-38-8(Hazardous Substances Data)

Upstream product

• 141550-13-2 4,4,5,5-tetramethyl-2-(3-methylbut-2-enyl)-1,3,2-dioxaborolane 
• 104-55-2 3-phenyl-propenal 
• 114067-34-4 (3-methyl-2-butenyl)trifluorosilane 
• 61209-24-3 (Z)-3-methyl-2-butenyltrichlorosilane 

Relevant articles and documents

REGIOSPECIFIC AND HIGHLY STEREOSELECTIVE ALLYLATION OF ALDEHYDES WITH ALLYLTRIFLUOROSILANE ACTIVATED BY FLUORIDE IONS.

Allyltrifluorosilane/CsF systems form pentacoordinate allylsiliconates which undergo chemoselective, regiospecific and highly stereoselective allylation of aldehydes, presumably via six-membered cyclic transition states.

Facile and highly stereoselective allylation of aldehydes using allyltrichlorosilanes in DMF

Allyltrichlorosilanes regioselectively react with aldehydes in N,N-dimethylformamide (DMF) without catalyst to afford the corresponding homoallylic alcohols in high yields. Syn and anti homoallylic alcohols are stereoselectively obtained from (Z)- and (E)