114092-60-3

Basic information

• Product Name: Benzene, 1-(2-bromoethenyl)-3-(trifluoromethyl)-, (Z)-
• CAS NO: 114092-60-3
• Molecular Formula: C9H6BrF3
• Molecular Weight: 251.046
• Mol File: 114092-60-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Benzene, 1-(2-bromoethenyl)-3-(trifluoromethyl)-, (Z)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-(2-bromoethenyl)-3-(trifluoromethyl)-, (Z)-(114092-60-3)
• EPA Substance Registry System: Benzene, 1-(2-bromoethenyl)-3-(trifluoromethyl)-, (Z)-(114092-60-3)

Safety Data

• Hazardous Substances Data: 114092-60-3(Hazardous Substances Data)

Upstream product

• 779-89-5 3-(trifluoromethyl)cinnamic acid 

Downstream Products

• 705-28-2 1-ethynyl-3-trifluoromethylbenzene 

Relevant articles and documents

Stereoselective synthesis of (E)-β-arylvinyl bromides by microwave-induced Hunsdiecker-type reaction

(E)-β-Arylvinyl bromides were readily prepared in a short reaction time (1-2 min) by microwave irradiation of the corresponding 3-arylpropenoic acids in the presence of N-bromosuccinimide and a catalytic amount of lithium acetate. Furthermore, two facile strategies for the efficient synthesis of (E)-β-bromo-4-arylethynylstyrene and (E)-β-bromo-4-arylstyrene have been developed by respectively combining Sonogashira and Suzuki coupling reaction with Hunsdiecker-type reaction. Formation of cis-α-bromo-β- lactone by microwave irradiation of cis-cinnamic acid with NBS provides a useful support for the mechanistic study of the present halodecarboxylation reaction. Georg Thieme Verlag Stuttgart.