114106-65-9

Basic information

• Product Name: Benzonitrile, 3-(1,3-dimethyl-1H-indol-2-yl)-4-hydroxy-
• CAS NO: 114106-65-9
• Molecular Formula: C17H14N2O
• Molecular Weight: 262.311
• Mol File: 114106-65-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Benzonitrile, 3-(1,3-dimethyl-1H-indol-2-yl)-4-hydroxy-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzonitrile, 3-(1,3-dimethyl-1H-indol-2-yl)-4-hydroxy-(114106-65-9)
• EPA Substance Registry System: Benzonitrile, 3-(1,3-dimethyl-1H-indol-2-yl)-4-hydroxy-(114106-65-9)

Safety Data

• Hazardous Substances Data: 114106-65-9(Hazardous Substances Data)

Upstream product

• 106-51-4 p-benzoquinone 
• 875-30-9 1,3-dimethylindole 
• 96802-32-3 diethyl 1-cyano-4-oxocyclohexa-2,5-dienyl phosphate 

Relevant articles and documents

Regiospesific Arylation of 1,4-Benzoquinone Cyanohydrin Phosphate: Synthesis of 3-Aryl-4-hydroxybenzonitriles

Reaction of 1,4-benzoquinones (1a,b) with diethyl phosphorocyanidate and lithium cyanide was found to give the monocyanophosphates (2a,b).When catalysed by BF3*OEt2, the cyanophosphates (2a,b) reacted with aromatic and heteroaromatic compounds (indole, thiophene, and furan derivatives) to give 3-aryl-4-hydroxybenzonitriles.Under the same conditions ethyl 1-methylindole-2-carboxylate and 2,5-dimethylfuran were converted into 6-oxobenzopyranoindole-2-carbonitriles (15a,b) and benzofuran-5-carbonitriles (22a,b) by reaction with the cyanophosphates (2a,b), respectively.