114247-78-8

Basic information

• Product Name: Cyclohexanone, 2-(acetyloxy)-2,6,6-trimethyl-, (S)-
• CAS NO: 114247-78-8
• Molecular Formula: C11H18O3
• Molecular Weight: 198.262
• Mol File: 114247-78-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Cyclohexanone, 2-(acetyloxy)-2,6,6-trimethyl-, (S)-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexanone, 2-(acetyloxy)-2,6,6-trimethyl-, (S)-(114247-78-8)
• EPA Substance Registry System: Cyclohexanone, 2-(acetyloxy)-2,6,6-trimethyl-, (S)-(114247-78-8)

Safety Data

• Hazardous Substances Data: 114247-78-8(Hazardous Substances Data)

Upstream product

• 546-67-8 lead(IV) tetraacetate 
• 88794-46-1 (-)-2,2,6-trimethyl-7-oxabicyclo[4.1.0]heptane-1-methanol 
• 103138-20-1 (S)-2,6-dimethyl-1-trimethylsiloxy-1-cyclohexene 

Downstream Products

• 81800-41-1 (S)-dihydroactinidiolide 

Relevant articles and documents

Lead(IV) acetate oxidative ring-opening of 2,3-epoxy primary alcohols: A new entry to optically active α-hydroxy carbonyl compounds

The treatment of 2,3-epoxy primary alcohols with lead(IV) acetate (LTA) leads to α-acetoxy aldehydes or α-acetoxy ketones, through the nucleophilic ring-opening of an intermediate oxonium and the subsequent carbon-carbon bond cleavage. This reaction repre

CONCISE ASYMMETRIC SYNTHESIS OF (5S, 6S)- AEGINETOLIDE AND (5S)- DIHYDROACTINIDIOLIDE

An asymmetric deprotonation reaction allows for short syntheses of the lactones (5S,6S)- Aeginetolide (1) and (5S)-Dihydroactinidiolide (2).