114300-83-3

Basic information

• Product Name: methyl (1α,5β,6β)-5-methoxy-2,6-dimethyl-2-cyclohexene-1-carboxylate
• CAS NO: 114300-83-3
• Molecular Weight: 198.262
• Mol File: 114300-83-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: methyl (1α,5β,6β)-5-methoxy-2,6-dimethyl-2-cyclohexene-1-carboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl (1α,5β,6β)-5-methoxy-2,6-dimethyl-2-cyclohexene-1-carboxylate(114300-83-3)
• EPA Substance Registry System: methyl (1α,5β,6β)-5-methoxy-2,6-dimethyl-2-cyclohexene-1-carboxylate(114300-83-3)

Safety Data

• Hazardous Substances Data: 114300-83-3(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 201230-82-2 carbon monoxide 
• 4190-06-1 1,5-dimethylcyclohexa-1,4-diene 

Relevant articles and documents

trans-Bis(5-methoxy-1-3-η3-cyclohexenyl)palladium Complexes by Palladium(II)-Promoted Addition of Methanol to 1,4-Cyclohexadienes. Synthesis of Methyl trans-5-Methoxy-2-cyclohexene-1-carboxylates by Subsequent Methoxycarbonylation

1,4-Cyclohexadienes in the presence of bis(acetonitrile)palladium dichloride in methanol are stereoselectively converted to trans-bis(5-methoxy-1-3-η3-cyclohexenyl)palladium chloride complexes.A series of substituted 1,4-cyclohexadienes was studied to determine the effects of substituents.Subsequent methoxycarbonylation regioselectively and stereoselectivity afforded the corresponding methyl trans-5-methoxy-2-cyclohexene-1-carboxylates.The two-reaction sequence can be coupled in a tandem reaction procedure.