114395-22-1Relevant articles and documents
ε2-Coordination in pentacoordinate iron complexes
Birk, Reiner,Berke, Heinz,Hund, Hans-Ulrich,Huttner, Gottfried,Zsolnai, Laszlo,et al.
, p. 397 - 410 (1989)
The reactions of the dinitrogen complexes μ-N22 (L = P(OMe)3 1a; P(O-i-Pr)3, 1b; PEt3, 1c with diphenylketene diphenyl-p-tolylketene imine and propionitrile give the η2-C,O ketene compounds Fe(CO)2L2Ph2C2O (L = P(OMe)3, 2a; P(O-i-Pr)3, 2b; PEt3, 2c) a ketene imine system Fe(CO)22Ph2C2N-p-tolyl (3 and the propionitrile substitution derivatives Fe(CO)2L2EtCN (L = P(OMe)3 4; PEt3, 5), respectively.The structures of 2c, 3 and 5a have been determined by X-ray diffraction.