114396-98-4

Basic information

• Product Name: N-benzoyl-N-allyl-7-aminocyclohepta-1,3,5-triene
• Synonyms: N-benzoyl-N-allyl-7-aminocyclohepta-1,3,5-triene
• CAS NO: 114396-98-4
• Molecular Weight: 251.328
• Mol File: 114396-98-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N-benzoyl-N-allyl-7-aminocyclohepta-1,3,5-triene(CAS DataBase Reference)
• NIST Chemistry Reference: N-benzoyl-N-allyl-7-aminocyclohepta-1,3,5-triene(114396-98-4)
• EPA Substance Registry System: N-benzoyl-N-allyl-7-aminocyclohepta-1,3,5-triene(114396-98-4)

Safety Data

• Hazardous Substances Data: 114396-98-4(Hazardous Substances Data)

Upstream product

• 27081-10-3 tropylium tetrafluoroborate 
• 98-88-4 benzoyl chloride 
• 114396-95-1 Allyl-cyclohepta-2,4,6-trienyl-amine 

Downstream Products

• 10283-95-1 N-allylbenzamide 
• 114397-07-8 N-benzoyl-N-allyl-3-aminocyclohepta-1,3,5-triene 
• 114397-06-7 N-benzoyl-3-azatricyclo<5.3.1.0^4,10>undeca-5,8-diene 

Relevant articles and documents

Competitive -Cycloaddition versus -Hydrogen Sigmatropy in a Cycloheptatriene. An Efficient Route to 3-Azatricyclo4,10>undeca-5,8-diene

Thermal rearrangements of N-acyl-7-aminocyclohepta-1,3,5-trienes 7b-e in octane or xylene provide -cycloaddition products 8b-e and -hydrogen sigmatropic rearrangement products 9b-e.The relative rate of formation for 8e/9e is 1.5 in refluxing octane.At a higher reaction temperature in xylene and longer reaction times, 7b afforded a second hydrogen-shift product 10b.No thermal -carbon shift products were observed from N-allyl cycloheptatrienes 9b-e or 10b in octane or xylene.The thermal behavior of 7b-e can be contrasted with that of O-allyl cyclohepta-1,3,5-triene 1.