114693-83-3

Basic information

• Product Name: rac-(R,R)-2,2-dimethylcyclohexane-1,3-diol
• Synonyms: rac-(R,R)-2,2-dimethylcyclohexane-1,3-diol
• CAS NO: 114693-83-3
• Molecular Weight: 144.214
• Mol File: 114693-83-3.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: rac-(R,R)-2,2-dimethylcyclohexane-1,3-diol(CAS DataBase Reference)
• NIST Chemistry Reference: rac-(R,R)-2,2-dimethylcyclohexane-1,3-diol(114693-83-3)
• EPA Substance Registry System: rac-(R,R)-2,2-dimethylcyclohexane-1,3-diol(114693-83-3)

Safety Data

• Hazardous Substances Data: 114693-83-3(Hazardous Substances Data)

Upstream product

• 562-13-0 2,2-dimethyl-1,3-cyclohexanedione 
• 16807-60-6 3-methoxycyclohex-2-en-1-one 
• 1193-55-1 2-methylcyclohexane-1,3-dione 

Downstream Products

• 35934-83-9 3,3-dimethyl-1,4-cyclohexadiene 

Relevant articles and documents

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Chemoenzymatic synthesis of both enantiomers of 3-hydroxy-2,2- dimethylcyclohexanone

(Chemical Equation Presented) The stereoselective acetylation of meso-2,2-dimethyl-1,3-cyclohexanediol by vinyl acetate in the presence of three lipases gave the (1R,3S)-monoester in high enantiomeric excess (ee ≥ 98%). The hydrolysis of the corresponding meso-diacetate in the presence of Candida antarctica lipase in phosphate buffer provided the opposite enantiomer. Optically active monoacetates were converted to both enantiomers of 3-hydroxy-2,2-dimethylcyclohexanone, a versatile chiral building block.

Elektroreduktion organischer Verbindungen, 14. Die elektrochemische Reduktion von 1,3-Bis(methansulfonyloxy)cyclohexanen.

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