114747-44-3Relevant articles and documents
Synthesis, characterization and photochromic studies in film of heterocycle-containing spirooxazines
Tan, Ting-Feng,Chen, Pei-Li,Huang, Hua-Ming,Meng, Ji-Ben
, p. 8192 - 8198 (2005)
A series of novel heterocycle-containing spirooxazines have been designed and synthesized, and their photochromic properties were investigated under flash photolysis and continuous irradiation in particular regard to the fatigue resistance, the lifetime of the colored merocyanine form in various solutions and polymers. Especially, the characteristics of two UV-sensitive spirooxazines dispersed polymethylmethacrylate thin-films were extensively studied. Detailed studies showed that general significant shifts in the λmax of the absorption spectra of the open forms, interesting fatigue resistances and emission fluorescene properties were observed.
One-pot synthesis of 6′-amino-substituted spirooxazines
Koshkin,Lokshin,Samat,Gromov,Fedorova
, p. 1876 - 1880 (2005)
A one-pot synthesis of 6′-amino-substituted spiroindolinonaphth[2,1- b][1,4]oxazines is developed through the condensation of 2-methylene-1,3,3- trimethylindoline derivatives and 1-amino-2-naphthol in the presence of different secondary amines and oxidizing agents using methanol or toluene as the solvent. The main advantage of the method is its simplicity, and starting from readily accessible reagents, it allows the preparation of amino derivatives of spironaphthoxazine with good yields under mild reaction conditions. Georg Thieme Verlag Stuttgart.
Red colouring photochromic 6′-substituted spiroindolinonaphth[2,1-b][1,4]oxazines
Rickwood,Marsden,Ormsby,Staunton,Wood,Hepworth,Gabbutt
, p. 17 - 24 (2007/10/02)
Electron donating/withdrawing substituents and electronegative centres have been successfully employed in substantially widening the range of photo-generated colours available in the spiroindolinonaphthoxazine class of photochromic materials.