114877-93-9

Basic information

• Product Name: (S)-1-(diphenylphosphino)-N-(1-(methoxycarbonyl)-2-methylpropyl)thioformamide
• CAS NO: 114877-93-9
• Molecular Weight: 359.429
• Mol File: 114877-93-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (S)-1-(diphenylphosphino)-N-(1-(methoxycarbonyl)-2-methylpropyl)thioformamide(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-1-(diphenylphosphino)-N-(1-(methoxycarbonyl)-2-methylpropyl)thioformamide(114877-93-9)
• EPA Substance Registry System: (S)-1-(diphenylphosphino)-N-(1-(methoxycarbonyl)-2-methylpropyl)thioformamide(114877-93-9)

Safety Data

• Hazardous Substances Data: 114877-93-9(Hazardous Substances Data)

Upstream product

• 6306-52-1 L-valine methylester hydrochloride 
• 72-18-4 L-valine 
• 114877-91-7 methyl (S)-2-isothiocyanato-3-methylbutanoate 
• 829-85-6 diphenylphosphane 

Relevant articles and documents

SYNTHESIS OF CHIRAL THIOCARBAMOYLPHOSPHINES DERIVED FROM AMINO ACIDS

The methylester hydrochlorides of the (S)-amino acids L-alanine (1a), L-phenylalanine (1b), L-valine (1c) and L-lysine (1d) were converted to the corresponding isothiocyanates 2a-d by thiophosgenation. 2a-d React with secondary phosphines and phosphine oxides to give the thiocarbamoylphosphines 3a-d and P-oxides 4a, b.