1150112-10-9Relevant articles and documents
A Fourfold Benzodehydroannuleno-Fused Porphyrazine
K?rte, Fabian,Bruhn, Clemens,Faust, Rüdigger
, p. 1620 - 1624 (2015)
Four benzodehydroannulene subunits were implemented on a dibenzoquinoxalinopoprhyrazine core using efficient palladium-mediated alkyne coupling and oxidative acetylene coupling on phenanthrene dione precursors. Despite the significant amount of strain in system, as evidenced by X-ray analysis of an immediate precursor, porphyrazine assembly leads to an extended model for N-doped graphyne with photosensitizing properties.
An extremely simple dibenzopentalene synthesis from 2-bromo-1- ethynylbenzenes using nickel(O) complexes: Construction of its derivatives with various functionalities
Kawase, Takeshi,Konishi, Akihito,Hirao, Yasukazu,Matsumoto, Kouzou,Kurata, Hiroyuki,Kubo, Takashi
experimental part, p. 2653 - 2661 (2009/12/03)
An extremely simple dibenzopentalene synthesis from readily available 2-bromo-1-ethynylbenzenes using a nickel(O) complex is described. Although the yields are moderate, the formation of three C-C bonds in a single process and the high availability of the