115094-66-1

Basic information

• Product Name: 2-Cyclopenten-1-one, 4-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-2-(phenylseleno)-, (R)-
• CAS NO: 115094-66-1
• Molecular Formula: C17H24O2SeSi
• Molecular Weight: 367.422
• Mol File: 115094-66-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-Cyclopenten-1-one, 4-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-2-(phenylseleno)-, (R)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Cyclopenten-1-one, 4-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-2-(phenylseleno)-, (R)-(115094-66-1)
• EPA Substance Registry System: 2-Cyclopenten-1-one, 4-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-2-(phenylseleno)-, (R)-(115094-66-1)

Safety Data

• Hazardous Substances Data: 115094-66-1(Hazardous Substances Data)

Upstream product

• 5707-04-0 Phenylselenyl chloride 
• 61305-35-9 (R)-4-((tert-butyldimethylsilyl)oxy)cyclopent-2-enone 

Downstream Products

• 82542-42-5 Methyl (Z)-7-<(3R)-3-<(tert-Butyldimethylsilyl)oxy>-5-oxo-1-cyclopentenyl>-5-heptenoate 
• 42541-96-8 Methyl (Z)-7-<(3R)-3-Hydroxy-5-oxo-1-cyclopentenyl>-5-heptenoate 

Relevant articles and documents

A New Route to the Prostaglandin Skeleton via Radical Alkylation. Synthesis of 6-Oxoprostaglandin E1

A new, mild, and efficient method for the construction of the prostanoid skeleton involving cuprate addition to α-(phenylseleno)cyclopentenones followed by radical-based coupling to the resulting products with allylstannane derivatives is described.The method is applied to the synthesis of 6-oxoprostaglandin E1, a biologically active and naturally occurring compound.