115095-28-8

Basic information

• Product Name: 15-(4-Dimethylamino-phenyl)-17-(4-nitro-phenyl)-17H-16,17-diaza-14-azonia-cyclopenta[a]phenanthrene; perchlorate
• Synonyms: 15-(4-Dimethylamino-phenyl)-17-(4-nitro-phenyl)-17H-16,17-diaza-14-azonia-cyclopenta[a]phenanthrene; perchlorate
• CAS NO: 115095-28-8
• Molecular Weight: 559.966
• Mol File: 115095-28-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 15-(4-Dimethylamino-phenyl)-17-(4-nitro-phenyl)-17H-16,17-diaza-14-azonia-cyclopenta[a]phenanthrene; perchlorate(CAS DataBase Reference)
• NIST Chemistry Reference: 15-(4-Dimethylamino-phenyl)-17-(4-nitro-phenyl)-17H-16,17-diaza-14-azonia-cyclopenta[a]phenanthrene; perchlorate(115095-28-8)
• EPA Substance Registry System: 15-(4-Dimethylamino-phenyl)-17-(4-nitro-phenyl)-17H-16,17-diaza-14-azonia-cyclopenta[a]phenanthrene; perchlorate(115095-28-8)

Safety Data

• Hazardous Substances Data: 115095-28-8(Hazardous Substances Data)

Upstream product

• 85-02-9 benzo[f]quinoline 
• 3155-30-4 4-(N,N-dimethylamino)benzaldehyde 4-nitrophenylhydrazone 

Relevant articles and documents

Electrochemical Synthesis of Heterocyclic Compounds. 17. Anodic Oxidation of Hydrazones in the Presence of Heteroaromatic and Schiff Bases

Anodic oxidation of a series of hydrazones in the presence of heteroaromatic and Schiff bases were performed in acetonitrile-tetraethylammonium perchlorate electrolyte solution at platinum using controlled potentials.As a result of four-electron oxidation several s-triazolopyridinium perchlorates (1-9), s-triazoloquinolinium perchlorate (10), s-triazoloisoquinolinium perchlorate (11), and s-triazolobenzoquinolinium perchlorate (12) were obtained in yields ranging from 30percent to 90percent.As a result of two-electron oxidation of -p-nitrophenylhydrazine (A) in the presence of imidazole and 1,2,4-triazole the azo derivatives 13 and 14 were obtained with high yields.As a result of two-electron oxidation of hydrazone A in the presence of Schiff bases the new Schiff bases 15-20 were obtained in high yields.On the bases of the electroanalytical and preparative results it is concluded that the electrochemical oxidation of hydrazone A in the presence of heteroaromatic and Schiff bases occurs through the formation of cation B, which is attacked by base as a nucleophile.This excludes the possibility of annelation of the heteroaromatics through nitrilimine as an intermediate.