115215-73-1Relevant articles and documents
Making the SF5 Group More Accessible: A Gas-Reagent-Free Approach to Aryl Tetrafluoro-λ6-sulfanyl Chlorides
Pitts, Cody Ross,Bornemann, Dustin,Liebing, Phil,Santschi, Nico,Togni, Antonio
supporting information, p. 1950 - 1954 (2019/01/25)
Modern pentafluorosulfanyl (SF5) chemistry has an Achilles heel: synthetic accessibility. Herein, we present the first approach to aryl-SF4Cl compounds (key intermediates in state-of-the-art aryl-SF5 synthesis) that overco
DBU-Mediated cleavage of aryl- and heteroaryl disulfides
Nyoni, Dubekile,Lobb, Kevin A.,Kaye, Perry T.,Caira, Mino R.
experimental part, p. 245 - 252 (2012/05/31)
The capacity of the nitrogen nucleophile, 1,8-diazabicyclo[5.4.0]undec-7- ene (DBU) to reduce aryl- and heteroaryl disulfides to the corresponding mercaptans is demonstrated. While dicarboxylated disulfide analogues afford the mono-DBU disulfide salts, as confirmed by X-ray crystallography, the corresponding methyl esters are cleaved normally. ARKAT-USA, Inc.