115319-79-4

Basic information

• Product Name: 3-hydroxy-2-methoxy-6-(methoxymethyl)-α-phenylbenzyl alcohol
• CAS NO: 115319-79-4
• Molecular Weight: 274.317
• Mol File: 115319-79-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3-hydroxy-2-methoxy-6-(methoxymethyl)-α-phenylbenzyl alcohol(CAS DataBase Reference)
• NIST Chemistry Reference: 3-hydroxy-2-methoxy-6-(methoxymethyl)-α-phenylbenzyl alcohol(115319-79-4)
• EPA Substance Registry System: 3-hydroxy-2-methoxy-6-(methoxymethyl)-α-phenylbenzyl alcohol(115319-79-4)

Safety Data

• Hazardous Substances Data: 115319-79-4(Hazardous Substances Data)

Upstream product

• 5533-03-9 2-methoxy-4-methoxymethylphenol 
• 100-52-7 benzaldehyde 

Relevant articles and documents

Metalation of Phenols. Synthesis of Benzoquinones by the Oxidative Degradation Approach

In a effort to explore the potential of so-called oxidative degradation approach for the synthesis of quinones, we have investigated the direct metalation of a number of simple phenols such as o- and p-hydroxybenzyl alcohols, benzyl methyl ethers and N,N-dimethylbenzylamines.Apparently, only those phenolic substrates having available both a coordinating group for chelation and an electron-withdrawing group in a 1,3-relationship are efficiently lithiated, by the action of n-BuLi, in a regioselective manner.Those positions on the aromatic nucleus just flanked by a coordinating, or an acid-base, group could be metalated by action of the t-BuLi/THP system, in favorable cases.