115378-00-2Relevant articles and documents
SYNTHETIC CONNECTIONS TO THE AROMATIC DIRECTED METALATION REACTION. FUNCTIONALIZED ARYL BORONIC ACIDS BY IPSO BORODESILYLATION. GENERAL SYNTHESES OF UNSYMMETRICAL BIPHENYLS AND m-TERPHENYLS
Sharp, M. J.,Cheng, W.,Snieckus, V.
, p. 5093 - 5096 (2007/10/02)
Aryl boronic acids 2a-d and 4a-d obtained by metalation-B(OMe)3 or metalation silylation-ipso borodesilylation sequences, participate in efficient Pdo-catalyzed cross coupling reactions with aryl bromides to give unsymmetrical biphenyls 3a-d and m-terphenyls 5a-d respectively.