115403-39-9Relevant articles and documents
Molibdenum-95 nuclear magnetic resonance studies on disubstituted molibdenum(0) carbonyls
Alyea, Elmer C.,Somogyvari, Arpad
, p. 397 - 400 (2007/10/02)
Molibdenum-95 nmr spectral data are reported for 40 cis- and trans-Mo(CO)4LL' compounds and the chemical shifts discussed in relation to a simplified Ramsey expression for the paramagnetic shielding term.The identification of mixtures of products of the type Mo(CO)6-nLn is shown to be easily accomplished by 95Mo nmr spectroscopy.The 95Mo chemical shifts provide a sensitive probe of structural and electronic effects, as illustrated for several cyclic nitrogen ligands as well as a range of phosphine ligands in the Mo(CO)4LL' complexes.