115731-73-2

Basic information

• Product Name: 3(CH₂CHCH₂)Ir(P(C₆H₅)3)2H⁽¹⁺⁾*PW₁₂O₄₀^(3-)={(CH₂CHCH₂)Ir(P(C₆H₅)3)2H}3PW₁₂O₄₀
• CAS NO: 115731-73-2
• Molecular Weight: 5153.8
• Mol File: 115731-73-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 3(CH₂CHCH₂)Ir(P(C₆H₅)3)2H⁽¹⁺⁾*PW₁₂O₄₀^(3-)={(CH₂CHCH₂)Ir(P(C₆H₅)3)2H}3PW₁₂O₄₀(CAS DataBase Reference)
• NIST Chemistry Reference: 3(CH₂CHCH₂)Ir(P(C₆H₅)3)2H⁽¹⁺⁾*PW₁₂O₄₀^(3-)={(CH₂CHCH₂)Ir(P(C₆H₅)3)2H}3PW₁₂O₄₀(115731-73-2)
• EPA Substance Registry System: 3(CH₂CHCH₂)Ir(P(C₆H₅)3)2H⁽¹⁺⁾*PW₁₂O₄₀^(3-)={(CH₂CHCH₂)Ir(P(C₆H₅)3)2H}3PW₁₂O₄₀(115731-73-2)

Safety Data

• Hazardous Substances Data: 115731-73-2(Hazardous Substances Data)

Upstream product

• 1517-51-7 3,3,3-d3-propene 
• 187737-37-7 propene 
• 115794-94-0 ((Ph₃P)2IrH₂)3PW₁₂O₄₀ 
• 1517-49-3 1,1-dideuteropropene 
• 1184-59-4 propene-2-d1 
• 2207-64-9 cyclopropane-d6 

Relevant articles and documents

Solid-state chemistry of molecular metal oxide clusters. Reactions of microporous [(Ph3P)2IrH2]3PW12O 40 with small organic molecules

The heterogeneous reactions of [(Ph3P)2IrH2]3PW12O 40 with CO, PF3, C2H4, C2H2, CH3CH=CH2, c-C5H8, C6H6, CH3C6H5, 2,3-dimethyl-1,3-butadiene, isoprene, butadiene, Me3SiH, C2F4, CF3CF=CF2, CF2=CFCl, CH3C(O)H, ethylene oxide, CH3OH, and H2O are described. The chemistry can be described in terms of either addition of iridium to a substrate C-H bond to form intermediates that may optionally eliminate H2 or addition of Ir-H to a C=C bond. It is proposed that these reactants gain access to essentially all of the iridium sites by dissolving in the hydrophobic regions of the lattice of the low surface area iridium oxometalate.