115755-20-9

Basic information

• Product Name: 2-[2-(4-Methoxy-phenyl)-ethyl]-3-methyl-thiazolidine
• Synonyms: 2-[2-(4-Methoxy-phenyl)-ethyl]-3-methyl-thiazolidine
• CAS NO: 115755-20-9
• Molecular Weight: 237.366
• Mol File: 115755-20-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-[2-(4-Methoxy-phenyl)-ethyl]-3-methyl-thiazolidine(CAS DataBase Reference)
• NIST Chemistry Reference: 2-[2-(4-Methoxy-phenyl)-ethyl]-3-methyl-thiazolidine(115755-20-9)
• EPA Substance Registry System: 2-[2-(4-Methoxy-phenyl)-ethyl]-3-methyl-thiazolidine(115755-20-9)

Safety Data

• Hazardous Substances Data: 115755-20-9(Hazardous Substances Data)

Upstream product

• 115755-16-3 2-[(E)-2-(4-Methoxy-phenyl)-vinyl]-3-methyl-thiazol-3-ium; iodide 
• 115755-03-8 1-(4-methoxyphenyl)-2-(2-thiazolyl)-(E)-ethene 

Downstream Products

• 20401-88-1 3-(4-methoxyphenyl)propional 

Relevant articles and documents

THIAZOLYLMETHYLENETRIPHENYLPHOSPHORANE AND ITS BENZO DERIVATIVE: STABLE AND PRACTICAL WITTIG REAGENTS FOR THE SYNTHESIS OF VINYLTHIAZOLES AND VINYLBENZOTHIAZOLES. TWO-CARBON HOMOLOGATION OF ALDEHYDES.

The title thiazolyl phosphorane is a stable yet quite reactive Wittig-type reagent which uppon reaction with various aldehydes affords vinylthiazoles, mainly or exclusively as E-isomers, in very good yields.Also the benzothiazolyl phosphorane derivative, unlike a literature report, prove to react with aldehydes.Vinylthyazoles subjected to formyl deblocking from thiazole nucleous afford two-carbon homologated satured aldehydes.As an example, one of these vinylthiazoles, viz. the β-phenyl derivative 8f, proves to add n-butyl lithium cuprate to give after the formyl deblocking 3-phenylheptanal.