115764-86-8

Basic information

• Product Name: [(Chloro-bis-trimethylsilanyl-methyl)-dimethyl-silanyl]-benzene
• Synonyms: [(Chloro-bis-trimethylsilanyl-methyl)-dimethyl-silanyl]-benzene
• CAS NO: 115764-86-8
• Molecular Weight: 329.105
• Mol File: 115764-86-8.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: [(Chloro-bis-trimethylsilanyl-methyl)-dimethyl-silanyl]-benzene(CAS DataBase Reference)
• NIST Chemistry Reference: [(Chloro-bis-trimethylsilanyl-methyl)-dimethyl-silanyl]-benzene(115764-86-8)
• EPA Substance Registry System: [(Chloro-bis-trimethylsilanyl-methyl)-dimethyl-silanyl]-benzene(115764-86-8)

Safety Data

• Hazardous Substances Data: 115764-86-8(Hazardous Substances Data)

Upstream product

• 768-33-2 phenyldimethylsilyl chloride 
• 108-86-1 bromobenzene 
• 15951-41-4 bis(trimethylsilyl)dichloromethane 
• 454-57-9 fluorodimethylphenylsilane 

Downstream Products

• 212064-80-7 C₂₂H₃₈Si₄ 
• 141868-82-8 {[(Methoxy-dimethyl-silanyl)-bis-trimethylsilanyl-methyl]-dimethyl-silanyl}-benzene 
• 90284-50-7 (phenyldimethylsilyl)(dimethyltrifluoroacetoxysilyl)bis(trimethylsilyl)methane 
• 115764-88-0 (diethyliodosilyl)(dimethylphenylsilyl)bis(trimethylsilyl)methane 
• 115764-87-9 (diethylsilyl)(dimethylphenylsilyl)bis(trimethylsilyl)methane 
• 77657-09-1 {[(Iodo-dimethyl-silanyl)-bis-trimethylsilanyl-methyl]-dimethyl-silanyl}-benzene 
• 212064-82-9 C₂₂H₃₇BrSi₄ 
• 75405-15-1 C₂₂H₃₇ClSi₄ 
• 77548-00-6 methyldiphenyl[(dimethylsilyl)bis(trimethylsilyl)methyl]silane 
• 90284-48-3 (dimethyltrifluoroacetoxysilyl)(methyldiphenylsilyl)bis(trimethylsilyl)methane 
• 131531-22-1 C₂₂H₃₇BrSi₄ 
• 78907-68-3 (dimethylphenylsilyl)bis(trimethylsilyl)methane 
• 125364-58-1 (dimethylphenylsilyl)(dimethylsilyl)bis(trimethylsilyl)methane 

Relevant articles and documents

Reactions of sterically hindered organozinc and organocadmium compounds containing functional silicon centres. Crystal structures of Zn2 and Cd2

The compound (Me3Si)2CCl2 was converted by treatment with BuLi/Et2O/THF and then with Me2HSiCl into (Me3Si)2CCl(SiMe2H).Further lithiation with BuLi gave LiC(SiMe3)2(SiMe2H), which reacted with ZnBr2 to yield Zn2.Thence, several new org

Reaction of (Me3Si)2C(SiMe2Ph)(SiEt2I) with AgBF4. 1,3-Migration of the Phenyl Group

The reaction of (Me3Si)2C(SiMe2Ph)(SiEt2I) with AgBF4 in Et2O has been shown to give a ca. 2:3 ratio of the unrearranged (Me3Si)2C(SiMe2Ph)(SiEt2F) and the rearranged (Me3Si)2C(SiEt2Ph)(SiMe2F).The reaction is thought to proceed via a cation, II, in which

1,3-Migration of a Phenyl Group via a Silicocation

The reaction of (Me3Si)2C(SiMe2Ph)(SiEt2I) with AgBF4 in Et2O has been shown to give a ca. 2:3 ratio of the unrearranged (Me3Si)2C(SiMe2Ph)(SiEt2F) and the rearranged (Me3Si)2C(SiMe2F)(SiEt2Ph); the reaction is thought to proceed via a Ph-bridged cation (