115843-51-1

Basic information

• Product Name: 1,2,3,3a,4,6a-hexahydro-5-<(4-methylphenyl)sulphonyl>-6-phenyl-1,2,4-methenopentalene
• CAS NO: 115843-51-1
• Molecular Weight: 348.466
• Mol File: 115843-51-1.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 1,2,3,3a,4,6a-hexahydro-5-<(4-methylphenyl)sulphonyl>-6-phenyl-1,2,4-methenopentalene(CAS DataBase Reference)
• NIST Chemistry Reference: 1,2,3,3a,4,6a-hexahydro-5-<(4-methylphenyl)sulphonyl>-6-phenyl-1,2,4-methenopentalene(115843-51-1)
• EPA Substance Registry System: 1,2,3,3a,4,6a-hexahydro-5-<(4-methylphenyl)sulphonyl>-6-phenyl-1,2,4-methenopentalene(115843-51-1)

Safety Data

• Hazardous Substances Data: 115843-51-1(Hazardous Substances Data)

Upstream product

• 536-74-3 phenylacetylene 
• 103-19-5 di(p-tolyl) disulfide 
• 63707-12-0 1-(4-methylphenylsulfanyl)-2-phenylethyne 
• 28995-88-2 1-methyl-4-((phenylethynyl)sulfonyl)benzene 
• 278-06-8 quadricyclo[2.2.1.0.0]heptane 
• 121-46-0 bicyclo[2.2.1]hepta-2,5-diene 

Downstream Products

• 55054-00-7 2-phenyl-tricyclo<4.2.1.0^2,5>nona-3,7-diene 

Relevant articles and documents

Ruthenium-catalyzed [2+2] cycloadditions of alkynyl sulfides and alkynyl sulfones

Ruthenium-catalyzed [2+2] cycloadditions of bicyclic alkenes with alkynyl sulfides and alkynyl sulfones were investigated. The sulfide and sulfone moieties were found to be compatible with the Ru-catalyzed cycloadditions, giving the corresponding cyclobut

REACTIVITY OF PHENYL(TOLYLSULFONYL)ACETYLENE TOWARDS DIENES AND HOMO-DIENES: CYCLOADDITIONS VERSUS FRAGMENTATION-ADDITION REACTIONS

Depending upon the diene, phenyl(tolylsulfonyl)acetylene (1a) affords the (4+2), the (2+2)-cycloadducts or products derived by 1,4-addition of the two fragments formed from homolytic cleavage of the carbon-sulfur bond.