115878-50-7

Basic information

• Product Name: Benzene, 1-[3-chloro-3-(phenylsulfinyl)propyl]-4-methoxy-
• CAS NO: 115878-50-7
• Molecular Formula: C16H17ClO2S
• Molecular Weight: 308.829
• Mol File: 115878-50-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Benzene, 1-[3-chloro-3-(phenylsulfinyl)propyl]-4-methoxy-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-[3-chloro-3-(phenylsulfinyl)propyl]-4-methoxy-(115878-50-7)
• EPA Substance Registry System: Benzene, 1-[3-chloro-3-(phenylsulfinyl)propyl]-4-methoxy-(115878-50-7)

Safety Data

• Hazardous Substances Data: 115878-50-7(Hazardous Substances Data)

Upstream product

• 738607-47-1 3-(4-methoxyphenyl)propyl phenyl sulfoxide 

Downstream Products

• 32588-84-4 1-(4-methoxyphenyl)nonane 
• 59623-12-0 3-(4'-methoxy phenyl)-propylchloride 
• 115878-68-7 4,7-Bis-benzenesulfinyl-1-(4-methoxy-phenyl)-heptan-3-one 
• 115878-63-2 1-(4-methoxyphenyl)-4,7-bis(phenylthio)-3-heptanone 
• 115878-72-3 (E)-1-(4-methoxyphenyl)-4,6-heptadien-3-one 
• 1739-13-5 N-phenyl-3-(4-methoxyphenyl)propane-1-amine 

Relevant articles and documents

Generation of magnesium carbenoids from 1-chloroalkyl phenyl sulfoxides with a Grignard reagent and applications to alkylation and olefin synthesis

Treatment of 1-chloroalkyl phenyl sulfoxides with a Grignard reagent at low temperature gave magnesium carbenoids in quantitative yields. The generated magnesium carbenoids were found to be stable at lower than -60°C for long periods of time and are reactive with Grignard reagents to give alkylated products. The reaction of the generated magnesium carbenoids with various kinds of lithium α-sulfonyl carbanions gave olefins with carbon-carbon bond-formation in good to high yields. This method offers a good way for the preparation of olefins. The scope and limitations of the above-mentioned reactions are described.