1159445-34-7

Basic information

• Product Name: methyl 3-((phenylimino)methyl)benzoate
• Synonyms: methyl 3-((phenylimino)methyl)benzoate
• CAS NO: 1159445-34-7
• Molecular Weight: 239.274
• Mol File: 1159445-34-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: methyl 3-((phenylimino)methyl)benzoate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 3-((phenylimino)methyl)benzoate(1159445-34-7)
• EPA Substance Registry System: methyl 3-((phenylimino)methyl)benzoate(1159445-34-7)

Safety Data

• Hazardous Substances Data: 1159445-34-7(Hazardous Substances Data)

Upstream product

• 52178-50-4 Methyl 3-formylbenzoate 
• 62-53-3 aniline 

Downstream Products

• 1159445-05-2 IrCl(η5-C5Me5)(methyl 3-(phenyliminomethyl)benzoate(1-)-κN,C6) 
• 1159445-06-3 RhCl(η5-C5Me5)(methyl 3-(phenyliminomethyl)benzoate(1-)-κN,C6) 

Relevant articles and documents

Reductive Umpolung of Carbonyl Derivatives with Visible-Light Photoredox Catalysis: Direct Access to Vicinal Diamines and Amino Alcohols via α-Amino Radicals and Ketyl Radicals

Visible-light-mediated photoredox-catalyzed aldimine-aniline and aldehyde-aniline couplings have been realized. The reductive single electron transfer (SET) umpolung of various carbonyl derivatives enabled the generation of intermediary ketyl and α-amino radical anions, which were utilized for the synthesis of unsymmetrically substituted 1,2-diamines and amino alcohols. Anilines can be coupled with aldimines or aldehydes in a visible-light-mediated photoredox-catalyzed process. Reductive single electron transfer (SET) umpolung of the carbonyl derivatives leads to the generation of intermediary ketyl and α-amino radical anions, which were used for the synthesis of unsymmetrically substituted 1,2-diamines and amino alcohols.