1160721-90-3Relevant articles and documents
Total synthesis of (-)-agelastatin A: The application of a sequential sigmatropic rearrangement
Hama, Naoto,Matsuda, Tomoki,Sato, Takaaki,Chida, Noritaka
supporting information; experimental part, p. 2687 - 2690 (2009/10/10)
An enantioselective total synthesis of (-)-agelastatin A from (-)-2,3-O-isopropylidene-D-threitol is described. The sequential Overman/Mislow-Evans rearrangement of the allylic bistrichloroimidate is the key step, which efficiently installed a diaminohydr