116159-23-0Relevant articles and documents
Studies in biomimetic polyether synthesis: Construction of an ABCD-ring subunit of etheromycin using polyepoxide cascade cyclisations
Paterson, Ian,Tillyer, Richard D.,Smaill, Jeff B.
, p. 7137 - 7140 (2007/10/02)
The diepoxides 8 and 9 were prepared by Horner-Emmons and aldol coupling reations from 21 and 13, respectively. The derived β-diketones 22 and 24 were cyclised under acidic conditions to generate the C1-C22 segment 7, which contains