1161830-97-2Relevant articles and documents
Regioselective rhodium(II)-catalyzed hydroaminations of propargylguanidines
Gainer, Morgan J.,Bennett, Nitasha R.,Takahashi, Yu,Looper, Ryan E.
supporting information; experimental part, p. 684 - 687 (2011/04/16)
Different than others: Dimeric rhodium(II) carboxylates uniquely catalyze the 6-endo-dig selective hydroamination of propargylguanidines while tranditional π-Lewis acids are typically 5-exo-dig selective (see scheme, oct=octanoate). Furthermore, this repr