116391-15-2

Basic information

• Product Name: methyl 2,6-di-O-benzyl-3-O-(2,3,4-tri-O-benzyl-α-L-fucopyranosyl)-α-D-galactopyranoside
• Synonyms: methyl 2,6-di-O-benzyl-3-O-(2,3,4-tri-O-benzyl-α-L-fucopyranosyl)-α-D-galactopyranoside
• CAS NO: 116391-15-2
• Molecular Weight: 790.951
• Mol File: 116391-15-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: methyl 2,6-di-O-benzyl-3-O-(2,3,4-tri-O-benzyl-α-L-fucopyranosyl)-α-D-galactopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 2,6-di-O-benzyl-3-O-(2,3,4-tri-O-benzyl-α-L-fucopyranosyl)-α-D-galactopyranoside(116391-15-2)
• EPA Substance Registry System: methyl 2,6-di-O-benzyl-3-O-(2,3,4-tri-O-benzyl-α-L-fucopyranosyl)-α-D-galactopyranoside(116391-15-2)

Safety Data

• Hazardous Substances Data: 116391-15-2(Hazardous Substances Data)

Upstream product

• 53685-11-3 (2R,3R,4S,5R,6S)-5-Benzyloxy-2-benzyloxymethyl-6-methoxy-tetrahydro-pyran-3,4-diol 
• 116514-50-2 ethyl 2,3,4-tri-O-benzyl-1-thio-β-L-fucopyranoside 
• 40269-01-0 methyl 3,4-O-isopropylidene-α-D-galactopyranoside 
• 53685-10-2 methyl 2,6-di-O-benzyl-3,4-O-isopropylidene-α-D-galactopyranoside 
• 3396-99-4 methyl α-D-galactopyranoside 
• 211801-54-6 p-methylphenyl 2,3,4-tri-O-benzyl-1-thio-β-L-fucopyranoside 
• 7404-35-5 1,2,3,4-tetra-O-acetyl-L-fucopyranose 
• 153658-86-7 (2S,3R,4R,5S,6R)-2-methyl-6-(p-tolylthio)tetrahydro-2H-pyran-3,4,5-triyl triacetate 
• 73-34-7 6-deoxy-L-galactose 
• 959774-86-8 p-methylphenyl 1-thio-β-L-fucopyranoside 

Relevant articles and documents

A novel O-fucosylation strategy preactivated by (p-Tol)2SO/Tf2O and its application for the synthesis of Lewis blood group antigen Lewisa

Based on a preactivation strategy using (p-Tol)2SO/Tf2O, a new O-fucosylation method with thioglycoside as donor under mild conditions was reported. High yields and excellent α-stereoselectivities of the fucosylation were obtained wi